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Desktop Sync no longer works/new exchange server

Previously, my Outlook 2003 used the same profile as my network login and desktop sync worked fine. Now, I log into outlook (exchange) with a different domain/user than I use to log into our network (and my machine). Since that change, Desktop sync has quit working. While attempting to sync, I receive "Outlook encountered an error trying to read a folder. Please check your folder settings.". If I go into settings and try to configure "Microsoft Outlook", the program freezes and must be killed manually. Is there a solution or workaround to my problem? Is this due to Desktop Sync running under my network login while Outlook is logged into the exchange server using a different login?
 
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