Can't get Custom URLs to post to WordPress blog.

Maybe a stupid question, but what email address do I use when editing the Custom URL? I've got a few - one email that is connected to my user account to log in to Ping.fm, one that I send emails to at Ping.fm to post messages, and one that is the admin email for the WordPress install I have. I can't get the Custom URL to work w/ my WordPress blog and I'm wondering if that's the problem. All I edited was the email section of the sample code... I didn't get any further than that yet.
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