Ability to add an alternative student e-mail address

Is there a way to add alternative e-mail addresses for students? Not all of them check the e-mail address assigned to them via our Google Apps domain.

We have gotten around this to some extent by adding an alternative address to their user setup in our Google Apps account, but... if their alternative address is also served by a Google Apps account (as many school districts are starting to be) it cannot be added as an alternative address. (FYI, our "students" are teachers.)
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